CPI Basics(417KB)
This page contains technical information about the photoacid generators, thermal acid generators, super strong bases, and thermal base generators handled by San-Apro.
Photo Acid Generators (PAGs) are substances that generate acid when
exposed to light.
This page describes the types of photo acid generators, their
reaction mechanisms, and selection criteria.
You can also download the PDF file from the following. The PDF version contains some outdated expressions and may differ from the latest information.
Photo Acid Generators (PAGs) are substances that generate acid
when exposed to light.
This page describes the types of photo acid generators, their
reaction mechanisms, and selection criteria.
There are two types of photoacid generator: ionic and nonionic. Ionic photoacid generators produce acid through a complex reaction process, while nonionic photoacid generators produce sulfonic acid directly. This section describes the differences in the mechanisms of acid generation by light.
There are two types of photoacid generators: ionic and
non-ionic. Ionic photoacid generators produce acid through a
complex reaction process, while non-ionic photoacid generators
produce sulfonic acid directly. The following describes the
differences in the mechanisms of acid generation by light.
The acids generated from photoacid generators are used in
various catalytic reactions. The main applications are
cationic polymerization of epoxy resins, deprotection
reactions of polyhydroxystyrene resins, and cross-linking
reactions of phenolic resins. These are widely applied in
semiconductor manufacturing and coating technology, and play
an important industrial role. The mechanisms of each reaction
are described below.
When selecting photoacid generators, it is important to choose a cation that is suitable for the wavelength of the light source to be used and has an appropriate molar absorption coefficient. When selecting an anion, the acid strength and solubility are the key factors. These selection criteria are described below.
Thermal Acid Generators (TAG) are substances that generate acid when
heated.
This page describes the TAGs in our lineup.
Since the first industrial production of a compound with this
structure by San-Apro in 1967, many researchers have introduced a
number of unique reactions.
The stability of DBU, its strong basicity
even now, new applications are being discovered one after another,
and many reports are being published.
*You can also download the PDF file from the following.
The PDF version contains some outdated expressions and may differ from the latest information.
U-CAT® and U-CAT SA® Series are high-performance thermal base generators that are used in a wide range of curing processes and chemical syntheses. These products are particularly suitable for applications that are sensitive to heat and pH, and enable precise material processing and efficient chemical reactions.
Epoxy resin curing accelerators speed up the curing process, increasing productivity while also improving the hardness and strength of the resin. San-Apro products are particularly suitable for LED encapsulants and electronic component encapsulants, and we will describe these applications.
Urethane catalysts, which are essential for the manufacture of polyurethane, are divided into two types: amine catalysts and metal catalysts. These catalysts have a significant impact on product quality even in small quantities, and their selection is directly linked to product value. Our U-CAT® series and U-CAT SA® series are compatible with a wide range of polyurethane applications.
*PDF download
(Japanese only)
You can download the handouts distributed at San-Apro exhibitions.
We introduce the latest product information, technical information,
and research results.
Sanapro's products and technologies have been featured in several research papers. From novel reactions using photoacid generators to pH and photo-responsive plastics, we contribute to the development of innovative materials.
Tokyo University of Pharmacy and Life Sciences
Mr.Hikaru
Yanai et al.
Mukaiyama Aldol reaction using...(2.5MB)
Mukaiyama Aldol...(2.5MB)
University of Hyogo Graduate School
Mr.Shinichi Yusa et al.
pH- and Photoresponsive...(571KB)
pH- and ...(571KB)
Mr.Shinichi Yusa, University of Hyogo
pH- and Photoresponsive Liquid Plasticine(More Information )
Osaka University Graduate School
Mr.Eguchi et al.
Photo-initiated living cation array control...(657KB)
Photo-initiated...(657KB)
Thank you for considering our products.
We provide support for product development by offering product characteristics, data and technical information to solve the challenges faced by product developers and researchers.
In recent years, there has been a worldwide tightening of regulations on per- and polyfluoroalkyl substances (PFAS), and we are focusing on the development of PFAS-free products to ensure that our customers can use them with peace of mind. Please also make use of our existing lineup of PFAS-free products.
*PFAS: OECD definition published in2021