A photoacid generator is a compound that generates an acid upon light irradiation, and this acid functions as a catalyst for cationic polymerization, cross-linking reactions, and deprotection reactions. They are particularly used as cationic polymerization initiators for light-curing resins and are utilized in a wide range of applications including paints, coatings, 3D printing resins, adhesives, and negative photoresists.
Overview and Function Map
The “CPI®-100 Series” is a PFAS FREE products. CPI®-100 Series” is a triarylsulfonium salt type photoacid generator (photocationic polymerization initiator) manufactured by our proprietary process. While conventional products contain large amounts of bis-sulfonium salts, the “CPI®-100 Series” has a high purity of monosulfonium salts, which provides excellent solubility in organic solvents and matrix resins and excellent one-component storage stability in cationic polymerizable compositions such as epoxy resins.
▶CPI-100P/110PThe CPI®-200 series has the same cationic structure as the CPI®-100 series and is our original high-purity sulfonium salt type photoacid generator. Although non-Sb-based, they have the same acid strength and cationic polymerization properties as SbF6 anionic products and excellent solubility in a variety of solvents and monomers; CPI-200K is available as a liquid and CPI-210S as a powder and has excellent storage stability
▶CPI-200K/210SThe CPI®-300 series is an i-line highly sensitive sulfonium salt type photoacid generator that uses a borate anion and has an acid strength equivalent to that of SbF6 anion products, despite being non-Sb based. This modification results in high cationic polymerization, low metal corrosion and low coloration of the cured product.
▶CPI-310BVC-1(development product) is a grade for transparent applications that suppresses absorption of visible light (g- and h-lines) and has large absorption only for i-rays. Because a special anion is used, the acid strength is equivalent to that of SbF6 anion products even though it is non-Sb-based, and it exhibits high cationic polymerization properties. It also has excellent solubility in a variety of solvents and monomers, including non-polar organic solvents.
▶VC-1 FGCPI®-400 series are sulfonium salt type photoacid generators with high sensitivity to i- and h-rays. CPI-410S and CPI-410B use a special anion and have the same acid strength as SbF6 anion products despite being non-Sb based. This provides high cationic polymerization and excellent solubility, which also contributes to low metal corrosion of the cured material.
▶CPI-410B ▶CPI-410SThe ES-1 series is a sulfonium salt type photoacid generator with high sensitivity to i- and h-rays, and has superior acid generation rate and solubility in organic compounds compared to the CPI-400 series. It uses non-Sb borate anions and has acid strength comparable to SbF6 anion products, providing high cationic polymerization and low metal corrosion of the cured material.
▶ES-1BES-2 series is a sulfonium salt type photoacid generator with high i-line sensitivity. It uses non-Sb borate anions, has acid strength equivalent to SbF₆ anion products, and exhibits high cationic polymerization and low metal corrosion of cured materials.
▶ES-2BThe IK series are a iodine salt type photoacid generators, which can be used in combination with a sensitizer for longer wavelengths. By using a special anion, it has the same acid strength as SbF6 anionic products despite being non-Sb-based, and it also achieves high cationic polymerization and low corrosion. It also features low coloration when heated at high temperatures.
▶IK-1FG ▶IK-1 ▶IK-20BNA-CS1 exhibits high transparency and solubility and is particularly sensitive to i-line.
▶NA-CS 1Thank you for considering our products.
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In recent years, there has been a worldwide tightening of regulations on per- and polyfluoroalkyl substances (PFAS), and we are focusing on the development of PFAS-free products to ensure that our customers can use them with peace of mind. Please also make use of our existing lineup of PFAS-free products.
*PFAS: OECD definition published in2021